Determination of orientational isomerism in rhodium(II) metallopeptides by pyrene fluorescence.
نویسندگان
چکیده
Rhodium(II) metallopeptides display useful secondary structure, self-assembly, and catalytic activity. The bis-peptide complexes exhibit subtle orientational isomerism that affects function, but is challenging to characterize. We report that pyrene excimer fluorescence measurements provide a conclusive proof of isomeric structure.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 10 41 شماره
صفحات -
تاریخ انتشار 2012